10.Anne Hathaway and Adam Shulman

Anne Hathaway had just gone through a terrible breakup that jeopardized her ability to trust. She was taking time to heal, then Adam Shulman suddenly came into the picture. The jewelry designer and producer sparked such strong feelings in the actress that she was willing to put her heart back on the line. They met through familiar friends in 2008, and their connection was “pretty instant” and intense. It gave the award-winning actress the courage to say “yes” to Shulman.

The couple gassed up their relationship in a private wedding ceremony in Big Sur, California, in September 2012. The Princess Diaries star revealed that she fell in love with Shulman at first sight. When she met him, the timing wasn’t perfect, yet she chose to trust her second chance at love. True enough, it is the kind of love she deserves all along.