26. Gwyneth Paltrow and Brad Falchuk

Gwyneth Paltrow—founder of Goop, red carpet royalty, and occasional country singer—needs no introduction. She goes by her first name and has been married to Brad Falchuk for the better part of a decade.

Gwyneth and Chris Martin declared their separation in March of 2014. Brad had separated from his partner, Suzanne Bukinik, a year before. As a result, the door marked Single and Ready to Mingle was wide open and they both walked in. Sparks started to fly during the set of Glee. Paltrow played substitute teacher Holly Holiday in the show, and even the two had met before; this time, they clicked. Fortunately, Falchuk and Paltrow made their first public appearance as a couple when they attended Robert Downey Jr.’s 50th birthday party. The couple declared their engagement in a joint statement, and months after, the two flew to Paltrow’s investment home in upstate New York to say “I do” in front of friends and family.